• Book titled Letters for a Nation written by Jawaharlal Nehru & Madhav Khosla published by Penguin Books
• World Gold Council and IIMA collaborated set up India Gold Policy Centre
• Biography My Name is Abu Salem authored by Hussain Zaidi released
• Kotak Mahindra Bank became first bank in India to fully own an insurance business
• New Species of bird Muscicapa flycatcher named after Indian ornithologist Navjot Sodhi
• First 3D-printed object developed in space by NASA and Made In Space Inc
• Boxer Manoj Kumar received Arjuna Award
• Union Government announced Swachh Bharat Kosh Operational Guidelines
• Guye Adola of Ethiopia won Airtel Half Marathon held in Delhi
• New exotic carnivorous plant Nepenthes zygon discovered at Kew Gardens in London
• Michael Phelps named Male Athlete of the year at the 2014 USA Swimming Golden Goggle Awards’
• Australian opener Philip Hughes died
• Kiran Gurrala appointed as CEO of CMDA
• Assam NGO Aaranyak nominated for UN lighthouse Activities award
• External Affairs Minister Sushma Swaraj visited United Arab Emirates
• Indian cyclist Deborah won four gold medals at Track Asia Cup 2014
• Sania Mirza appointed as UN Women Goodwill Ambassador for South Asia
• Indian dairy sector observed 26 November as National Milk Day
• WTO, WASTE and FINISH signed MoU to end open defecation in India
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• Haryana Government reduced retirement age of government employees from 60 to 58
• Adani power signed binding agreement with Avantha group to buy its Korba West Power Co Ltd unit
• US Defence Secretary Chuck Hagel resigned
• West Bengal Governor KN Tripathi appointed as Governor of Bihar
• Bilal Tanweer won Shakti Bhatt First Book Prize 2014
• Who has been appointed as 21^st chief of Staff of the Israel Defence Forces: Major General Gadi Eizenkot
• RBI eased gold imports & scrapped 80: 20 scheme
• AP government and METI signed MoU to promote FDI in AP
• RBI issued final guidelines for the Bharat Bill Payment System
• Next China-India War authored by General S. Padmanabhan released
• WTO adopted Trade Facilitation Agreement
• Union Government nominated Rajiv Mehrishi as Director on RBI Central Board
• NASA celebrated 50^th Anniversary of First Mars Mission, Mariner
• Indian and Mozambique signed MoU for cooperation in Oil and Gas sector
• Iconic Mexican comedian Chespirito died at 85
• 37^th Jamnalal Bajaj Foundation Awards for the year 2014 presented
• RBI released guidelines for Licensing of Payments Banks
• 18^th SAARC Summit concluded in Kathmandu, Nepal
• 19^th Summit will be held at Islamabad, Pakisthan 2016
• Historian Tapan Raychaudhuri died
• Who has been appointed as new Secretary General of Lok Sabha- Anoop Mishra
• Book Titled Your Dreams are Mine Now: She Showed him What Love was released
• Rajya Sabha passed Apprentices (Amendment) Bill, 2014
• Crime Novelist Physsis Dorothy James died at the age of 94
• Namsai became the 18^th district of Arunachal Pradesh
• Union Ministry of Sports honored Olympics Gold winning Hockey Team of 1964
• SBI Mutual Fund announced to launch Shariah Equity Fund
• Union Government launched Electronic Travel Authorization Scheme for 43 countries
• Bharti Airtel launched 4G Services in Seychelles
• Delhi & District Sixth P-8I maritime Patrol aircraft to India
• Pakistani actress Veena Malik sentenced to 26 years in Jail for blasphemy
• Vehicles older than 15-years not permitted to ply on Delhi roads: NGT
• Israeli Cabinet passed Jewish Nation-State Bill
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• President Pranab Mukherjee penned a book titled The Dramatic Decade on 1970s era
• Shah Rukh Khan named as Brand Ambassador of DHFL
• Legendary Kathak danseuse Sitara Devi died
• Who has been chosen as the next chairperson of PCI- Chandramauli Kumar
• Who won FIDE World Chess Championship 2014- Magnus Carlsen
• Raghuvir Nevrekar who died recently belongs to-  Senior Marathi Actor
• Who has been appointed as Advocate General of Maharashtra- Sunil Manohar
• Adidas appointed Tushar Gokuldas as Brand Director of Emerging Markets
• Pope Francis conferred sainthood on Father Chavara Achen & Sister Euphrasia
• World bank released report Turn Down the Heat: Confronting the New Climate Normal
• Ex-Washington DC mayor Marion Shepilov Barry Jr died
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• Three day International Toilet festival was inaugurated in Delhi
• Neha Gupta won International Children’s Peace Prize
• Ajim Premji Pjilanthropic Initiative launched to fund non-profit organizations
• Who has appointed as the Chairman of UPSC- Deepak Gupta
• Gujarat CM Anandiben Patel launched MLA Adarsh Gram Yojana
• Lewis Hamilton won Abu Dhabi Grand Prix to become the F1 World champion for second time
• Former Union Minister Murli Deora died
• Who won Abu Dhabi Grand Prix to become the F1 World champion for second time- Lewis Hamilton
• Former Union Minister Murli Deora died
• World Fisheries Day observed across the world on 21 November
• Prime Minister Narendra Modi visited Fiji
• India won 3^rd SAFF Women’s Championship in Islamabad
• Who received Col CK Nayudu Lifetime achievement award- Dilip Vengsarkar
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• Who will be the chief guest of India’s Republic Day 2015- US President Barack Obama
• Prime Minister Narendra Modi visited Australia
• Giriraj Singh assumed charge as Minister of state at MSME Ministry
• Who has been resigned as Managing Director and CEO of FTIL- Jignesh Shah
• Mathematician Alexander Grothendieck died
• Which bank won Custodian of the year 2014 award- Deutsche Bank
• Which countries signed Defence Cooperation Agreement- Pakistan and Russia
• Union Cabinet approved signing of three SAARC agreements
• Who conferred with Indian Film Personality of the year 2014 award at IFFI- Rajinikant

 IIT-JEE Advanced 2014-2015 Syallabus

1.  IIT  Suggested Syallabus: Chemistry

CHEMISTRY

• General topics: Concept of atoms and molecules; Dalton’s atomic theory; Mole concept; Chemical formulae; Balanced chemical equations; Calculations (based on mole concept) involving common oxidation-reduction, neutralisation, and displacement reactions; Concentration in terms of mole fraction, molarity, molality and normality.                                                                 
• Gaseous and liquid states: Absolute scale of temperature, ideal gas equation; Deviation from ideality, van der Waals equation; Kinetic theory of gases, average, root mean square and most probable velocities and their relation with temperature; Law of partial pressures; Vapour pressure; Diffusion of gases.                                                                                             
• Atomic structure and chemical bonding:  Bohr model, spectrum of hydrogen atom, quantum numbers; Wave-particle duality, de Broglie hypothesis; Uncertainty principle; Qualitative quantum mechanical picture of hydrogen atom, shapes of s, p and d orbitals; Electronic configurations of elements (up to atomic number 36); Aufbau principle; Pauli’s exclusion principle and Hund’s rule; Orbital overlap and covalent bond; Hybridisation involving s, p and d orbitals only; Orbital energy diagrams for homonuclear diatomic species;  Hydrogen bond; Polarity in molecules, dipole moment (qualitative aspects only); VSEPR model and shapes of molecules (linear, angular, triangular, square planar, pyramidal, square pyramidal, trigonalbipyramidal, tetrahedral and octahedral).                                                                                            
• Energetics: First law of thermodynamics; Internal energy, work and heat, pressure-volume work; Enthalpy, Hess’s law; Heat of reaction, fusion and vapourization; Second law of thermodynamics; Entropy; Free energy; Criterion of spontaneity.                                                                                    
• Chemical equilibrium:Law of mass action; Equilibrium constant, Le Chatelier’s principle (effect of concentration, temperature and pressure); Significance of ΔG and ΔG0 in chemical equilibrium; Solubility product, common ion effect, pH and buffer solutions;  Acids and bases (Bronsted and Lewis concepts); Hydrolysis of salts.                                                                              
• Electrochemistry: Electrochemical cells and cell reactions; Standard electrode potentials; Nernst equation and its relation to ΔG; Electrochemical series, emf of galvanic cells; Faraday’s laws of electrolysis; Electrolytic conductance, specific, equivalent and molar conductivity, Kohlrausch’s law; Concentration cells.                                                                                                        
• Chemical kinetics:  Rates of chemical reactions; Order of reactions; Rate constant; First order reactions; Temperature dependence of rate constant (Arrhenius equation).                                        
• Solid state: Classification of solids, crystalline state, seven crystal systems (cell parameters a, b, c, α, β, γ), close packed structure of solids (cubic), packing in fcc, bcc and hcp lattices; Nearest neighbours, ionic radii, simple ionic compounds, point defects.                                            
• Solutions:  Raoult’s law; Molecular weight determination from lowering of vapour pressure, elevation of boiling point and depression of freezing point.                                                                           
• Surface chemistry:  Elementary concepts of adsorption (excluding adsorption isotherms); Colloids: types, methods of preparation and general properties; Elementary ideas of emulsions, surfactants and micelles (only definitions and examples).                                                       
• Nuclear chemistry:  Radioactivity: isotopes and isobars; Properties of α, β and γ rays; Kinetics of radioactive decay (decay series excluded), carbon dating; Stability of nuclei with respect to proton-neutron ratio; Brief discussion on fission and fusion reactions.

• Isolation/preparation and properties of the following non-metals: Boron, silicon, nitrogen, phosphorus, oxygen, sulphur and halogens; Properties of allotropes of carbon (only diamond and graphite), phosphorus and sulphur.                                                  
• Preparation and properties of the following compounds: Oxides, peroxides, hydroxides, carbonates, bicarbonates, chlorides and sulphates of sodium, potassium, magnesium and calcium; Boron: diborane, boric acid and borax; Aluminium: alumina, aluminium chloride and alums; Carbon: oxides and oxyacid (carbonic acid); Silicon: silicones, silicates and silicon carbide;  Nitrogen: oxides, oxyacids and ammonia; Phosphorus: oxides, oxyacids (phosphorus acid, phosphoric acid) and phosphine; Oxygen: ozone and hydrogen peroxide; Sulphur: hydrogen sulphide, oxides, sulphurous acid, sulphuric acid and sodium thiosulphate; Halogens: hydrohalic acids, oxides and oxyacids of chlorine, bleaching powder; Xenon fluorides.                                                                                                                                                                   
• Transition elements (3d series): Definition, general characteristics, oxidation states and their stabilities, colour (excluding the details of electronic transitions) and calculation of spin-only magnetic moment; Coordination compounds: nomenclature of mononuclear coordination compounds, cis-trans and ionisation isomerisms, hybridization and geometries of mononuclear coordination compounds (linear, tetrahedral, square planar and octahedral).                                                                                                                                                                
• Preparation and properties of the following compounds: Oxides and chlorides of tin and lead; Oxides, chlorides and sulphates of Fe2+, Cu2+ and Zn2+; Potassium permanganate, potassium dichromate, silver oxide, silver nitrate, silver thiosulphate.                      
• Ores and minerals: Commonly occurring ores and minerals of iron, copper, tin, lead, magnesium, aluminium, zinc and silver.                                                                                                                                                             
• Extractive metallurgy: Chemical principles and reactions only (industrial details excluded); Carbon reduction method (iron and tin); Self reduction method (copper and lead); Electrolytic reduction method (magnesium and aluminium); Cyanide process (silver and gold).      
• Principles of qualitative analysis: Groups I to V (only Ag+, Hg2+, Cu2+, Pb2+, Bi3+, Fe3+, Cr3+,  Al3+, Ca2+, Ba2+, Zn2+, Mn2+ and Mg2+); Nitrate, halides (excluding fluoride), sulphate and sulphide.                                                                                                                                                                                                                                                                 Organic chemistry                                                                                                                                                                                             
• Concepts: Hybridisation of carbon; σ and π-bonds; Shapes of simple organic molecules; Structural and geometrical isomerism;  Optical isomerism of compounds containing up to two asymmetric centres, (R,S and E,Z nomenclature excluded); IUPAC nomenclature of simple organic compounds (only hydrocarbons, mono-functional and bi-functional compounds);                 Conformations of ethane and butane (Newman projections); Resonance and hyperconjugation; Keto-enoltautomerism; Determination of empirical and molecular formulae of simple compounds (only combustion method); Hydrogen bonds: definition and their effects on physical properties of alcohols and carboxylic acids; Inductive and resonance effects on acidity and basicity of organic acids and bases; Polarity and inductive effects in alkyl halides; Reactive intermediates produced during homolytic and heterolytic bond cleavage;  Formation, structure and stability of carbocations, carbanions and free radicals.                                                                                                              
• Preparation, properties and reactions of alkanes: Homologous series, physical properties of alkanes (melting points, boiling points and density); Combustion and halogenation of alkanes; Preparation of alkanes by Wurtz reaction and decarboxylation reactions.                                                                   
• Preparation, properties and reactions of alkenes and alkynes: Physical properties of alkenes and alkynes (boiling points, density and dipole moments); Acidity of alkynes; Acid catalysed hydration of alkenes and alkynes (excluding the stereochemistry of addition and elimination); Reactions of alkenes with KMnO4 and ozone; Reduction of alkenes and alkynes; Preparation of alkenes and alkynes by elimination reactions; Electrophilic addition reactions of alkenes with X2, HX, HOX and H2O (X=halogen);  Addition reactions of alkynes; Metal acetylides.                                                                                     
• Reactions of benzene: Structure and aromaticity; Electrophilic substitution reactions: halogenation, nitration, sulphonation, Friedel-Crafts alkylation and acylation; Effect of o-, m- and p-directing groups in monosubstituted benzenes.                                                                                                              
• Phenols: Acidity, electrophilic substitution reactions (halogenation, nitration and sulphonation); Reimer-Tieman reaction, Kolbe reaction.                                                                                                                                            
• Characteristic reactions of the following (including those mentioned above): Alkyl halides: rearrangement reactions of alkyl carbocation, Grignard reactions,  nucleophilic substitution reactions;  Alcohols: esterification, dehydration and oxidation, reaction with sodium, phosphorus halides, ZnCl2/concentrated HCl, conversion of alcohols into aldehydes and ketones; Ethers: Preparation by Williamson’s  Synthesis; Aldehydes and Ketones: oxidation, reduction, oxime and hydrazone formation; aldol condensation, Perkin reaction; Cannizzaro reaction; haloform reaction and nucleophilic addition reactions (Grignard addition);  Carboxylic acids: formation of esters, acid chlorides and amides, ester hydrolysis; Amines: basicity of substituted anilines and aliphatic amines, preparation from nitro compounds, reaction with nitrous acid, azo coupling reaction of diazonium salts of aromatic amines, Sandmeyer and related reactions of diazonium salts; carbylamine reaction; Haloarenes: nucleophilic aromatic substitution in haloarenes and substituted haloarenes (excluding Benzyne mechanism and Cine substitution).                                                                                                                                                            
• Carbohydrates: Classification; mono- and di-saccharides (glucose and sucrose); Oxidation, reduction, glycoside formation and hydrolysis of sucrose.                                                                                                    
• Amino acids and peptides: General structure (only primary structure for peptides) and physical properties.
• Properties and uses of some important polymers: Natural rubber, cellulose, nylon, teflon and PVC.                                                                                                                                   
• Practical organic chemistry: Detection of elements (N, S, halogens); Detection and identification of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl, amino and nitro; Chemical methods of separation of mono-functional organic compounds from binary mixtures.                                                                                                                                                                                                                                            

• MATHEMATICS                                                         
  
                                                                                      Algebra                                                         
• Algebra of complex numbers, addition, multiplication, conjugation, polar representation, properties of modulus and principal argument, triangle inequality, cube roots of unity, geometric interpretations.
• Quadratic equations with real coefficients, relations between roots and coefficients, formation of quadratic equations with given roots, symmetric functions of roots.
• Arithmetic, geometric and harmonic progressions, arithmetic, geometric  and harmonic means, sums of finite arithmetic and geometric progressions, infinite geometric series, sums of squares and cubes of the first n natural numbers.
• Logarithms and their properties.
• Permutations and combinations, Binomial theorem for a positive integral index, properties of binomial coefficients.
• Matrices as a rectangular array of real numbers, equality of matrices, addition, multiplication by a scalar and product of matrices, transpose of a matrix, determinant of a square matrix of order up to three, inverse of a square matrix of order up to three, properties of these matrix operations, diagonal, symmetric and skew-symmetric matrices and their properties, solutions of simultaneous linear equations in two or three variables.
• Addition and multiplication rules of probability, conditional probability, Bayes Theorem, independence of events, computation of probability of events using permutations and combinations.                                                                                                                                                                                                                                                                                           Trigonometric    
• Trigonometric functions, their periodicity and graphs, addition and subtraction formulae, formulae involving multiple and sub-multiple angles, general solution of trigonometric equations.
• Relations between sides and angles of a triangle, sine rule, cosine rule, half-angle formula and the area of a triangle, inverse trigonometric functions (principal value only).

Analytical Geometey

• Two dimensions: Cartesian coordinates, distance between two points, section formulae, shift of origin.
• Equation of a straight line in various forms, angle between two lines, distance of a point from a line; Lines through the point of intersection of two given lines, equation of the bisector of the angle between two lines, concurrency of lines;  Centroid, orthocentre, incentre and circumcentre of a triangle.
• Equation of a circle in various forms, equations of tangent, normal and chord.
• Parametric equations of a circle, intersection of a circle with a straight line or a circle, equation of a circle through the points  of  intersection of two circles and those of a circle and a straight line.
• Equations of a parabola, ellipse and hyperbola in standard form, their foci, directrices and eccentricity, parametric equations, equations of tangent and normal.
• Locus Problems.
• Three dimensions: Direction cosines and direction ratios, equation of a straight line in space, equation of a plane, distance of a point from a plane.

Differential Calculus

• Real valued functions of a real variable, into, onto and one-to-one functions, sum, difference, product and quotient of two functions, composite functions, absolute value, polynomial, rational, trigonometric, exponential and logarithmic functions.
• Limit and continuity of a function, limit and continuity of the sum, difference, product and quotient of two functions, L’Hospital rule of evaluation of limits of functions.
• Even and odd functions, inverse of a function, continuity of composite functions, intermediate value property of continuous functions.
• Derivative of a function, derivative of the sum, difference, product and quotient of two functions, chain rule, derivatives of polynomial, rational, trigonometric, inverse trigonometric, exponential and logarithmic functions.
• Derivatives of implicit functions, derivatives up to order two, geometrical interpretation of the derivative, tangents and normals, increasing and decreasing functions, maximum and minimum values of a function, Rolle’s Theorem and Lagrange’s Mean Value Theorem.

Integral Calculus

• Integration as the inverse process of differentiation, indefinite integrals of standard functions, definite integrals and their properties, Fundamental Theorem of Integral Calculus.
• Integration by parts, integration by the methods of substitution and partial fractions, application of definite integrals to the determination of areas involving simple curves.
• Formation of ordinary differential equations, solution of homogeneous differential equations, separation of variables method, linear first order differential equations.

Vectors

• Addition of vectors, scalar multiplication, dot and cross products, scalar triple products and their geometrical interpretations.

Physics 

 General

• Units and dimensions, dimensional analysis; least count, significant figures; Methods of measurement and error analysis for physical quantities pertaining to the following experiments: Experiments based on using Verniercalipers and screw gauge (micrometer), Determination of g using simple pendulum, Young’s modulus by Searle’s method, Specific heat of a liquid using calorimeter, focal length of a concave mirror and a convex lens using u-v method, Speed of sound using resonance column, Verification of Ohm’s law using voltmeter and ammeter, and specific resistance of the material of a wire using meter bridge and post office box.

Mechanics

• Kinematics in one and two dimensions (Cartesian coordinates only), projectiles; Uniform Circular motion; Relative velocity.                    
• Newton’s laws of motion; Inertial and uniformly accelerated frames of reference; Static and dynamic friction; Kinetic and potential energy; Work and power; Conservation of linear momentum and mechanical energy.
• Systems of particles; Centre of mass and its motion; Impulse; Elastic and inelastic collisions.
• Law of gravitation; Gravitational potential and field; Acceleration due to gravity; Motion of planets and satellites in circular orbits; Escape velocity.
• Rigid body, moment of inertia, parallel and perpendicular axes theorems, moment of inertia of uniform bodies with simple geometrical shapes; Angular momentum; Torque; Conservation of angular momentum; Dynamics of rigid bodies with fixed axis of rotation; Rolling without slipping of rings, cylinders and spheres; Equilibrium of rigid bodies; Collision of point masses with rigid bodies.
• Linear and angular simple harmonic motions.
• Hooke’s law, Young’s modulus.
• Pressure in a fluid; Pascal’s law; Buoyancy; Surface energy and surface tension, capillary rise; Viscosity (Poiseuille’s equation excluded), Stoke’s law; Terminal velocity, Streamline flow, equation of continuity, Bernoulli’s theorem and its applications.
• Wave motion (plane waves only), longitudinal and transverse waves, superposition of waves; Progressive and stationary waves; Vibration of strings and air columns; Resonance; Beats; Speed of sound in gases; Doppler effect (in sound).

Thermal physics

• Thermal expansion of solids, liquids and gases; Calorimetry, latent heat; Heat conduction in one dimension; Elementary concepts of convection and radiation; Newton’s law of cooling; Ideal gas laws; Specific heats (Cv and Cp for monoatomic and diatomic gases); Isothermal and adiabatic processes, bulk modulus of gases; Equivalence of heat and work; First law of thermodynamics and its applications (only for ideal gases); Blackbody radiation: absorptive and emissive powers; Kirchhoff’s law; Wien’s displacement law, Stefan’s law.

Electricity And Magnetism

• Coulomb’s law; Electric field and potential; Electrical potential energy of a system of point charges and of electrical dipoles in a uniform electrostatic field; Electric field lines; Flux of electric field; Gauss’s law and its application in simple cases, such as, to find field due to infinitely long straight wire, uniformly charged infinite plane sheet and uniformly charged thin spherical shell.
• Capacitance; Parallel plate capacitor with and without dielectrics; Capacitors in series and parallel; Energy stored in a capacitor.
• Electric current; Ohm’s law; Series and parallel arrangements of resistances and cells; Kirchhoff’s laws and simple applications; Heating effect of current.
• Biot–Savart’s law and Ampere’s law; Magnetic field near a current-carrying straight wire, along the axis of a circular coil and inside a long straight solenoid; Force on a moving charge and on a current-carrying wire in a uniform magnetic field.
• Magnetic moment of a current loop; Effect of a uniform magnetic field on a current loop; Moving coil galvanometer, voltmeter, ammeter and their conversions.
• Electromagnetic induction: Faraday’s law, Lenz’s law; Self and mutual inductance; RC, LR and LC circuits with d.c. and a.c. sources.

Optics

• Rectilinear propagation of light; Reflection and refraction at plane and spherical surfaces; Total internal reflection; Deviation and dispersion of light by a prism; Thin lenses; Combinations of mirrors and thin lenses; Magnification.
• Wave nature of light: Huygen’s principle, interference limited to Young’s double-slit experiment.

Modern Physics

• Rectilinear propagation of light; Reflection and refraction at plane and spherical surfaces; Total internal reflection; Deviation and dispersion of light by a prism; Thin lenses; Combinations of mirrors and thin lenses; Magnification.
• Wave nature of light: Huygen’s principle, interference limited to Young’s double-slit experiment.

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